Redlin H., Voigt J., Hillmann F.
The knowledge of the electronic excited states dynamics in light harvesting
pigment-protein complexes is most essential for the understanding of structure
function relationship in these complexes at molecular level. Improved structural
data as obtained in the last years for LH2 of purple bacteria and LHC II
of higher plants, an increasing number of spectroscopic data, especially
those with fs and ps time resolution, as well as improved quantum mechanical
methods give the basis to discuss the energy transfer in photosynthetic
antenna complexes more generally beyond the mostly used model of incoherent
Forster transfer between localized chlorophyll states.
New experimental results for LHC II of higher plants are discussed as
well from fs time resolved measurements as from measurements in the frequency
domain especially with respect to the exciton-phonon interaction. It is
shown that the energy transfer can adequately be described in terms of
the model of extended exciton states weakly coupled to the heat bath and
the relaxation between them.